VideoInsert
VideoInsert[video, t -> new] inserts the video new at time t.
VideoInsert[video, {t1, t2, ...} -> new]inserts the same video at multiple positions.VideoInsert[video, {t1 -> new1, ...}]inserts multiple videos at different positions.
Examples
Insert at time t:
VideoInsert[video1, Quantity[5, "Seconds"] -> video2]Multiple insertions:
VideoInsert[mainVideo, {
Quantity[2, "Seconds"] -> clip1,
Quantity[8, "Seconds"] -> clip2
}]Please visit the official Wolfram Language Reference for more details.