FormatValues
FormatValues[f] gives a list of transformation rules corresponding to all printing formats (values for Format[f[x, ...], ...], etc.) defined for the symbol f.
Examples
Define a format for a symbol:
Format[mySymbol[x_]] := Framed[x]
FormatValues[mySymbol]Check format values for a built-in symbol:
FormatValues[Plus]Please visit the official Wolfram Language Reference for more details.