OuterPolygon
OuterPolygon[poly] gives the outer polygon of the polygon poly.
Examples
Get the outer polygon of a polygon with a hole:
OuterPolygon[Polygon[{{{0,0},{1,0},{1,1},{0,1}},{{0.2,0.2},{0.8,0.2},{0.8,0.8},{0.2,0.8}}}]]
(* Polygon[{{0,0},{1,0},{1,1},{0,1}}] *)Please visit the official Wolfram Language Reference for more details.