VertexList
VertexList[g] gives the list of vertices in graph g.
Examples
Get vertices from a graph:
g = Graph[{1 -> 2, 2 -> 3, 3 -> 1}]
VertexList[g]
(* {1, 2, 3} *)
VertexList[CompleteGraph[5]]
(* {1, 2, 3, 4, 5} *)Please visit the official Wolfram Language Reference for more details.