PolyhedronAngle
PolyhedronAngle[poly,p] gives the solid angle at the point p and spanned by edges with common point p.
PolyhedronAngle[poly,e] gives the dihedral angle between the two faces with common edge e.
Examples
Find the solid angle at a vertex of a tetrahedron:
PolyhedronAngle[Tetrahedron[], {0, 0, 0}]Please visit the official Wolfram Language Reference for more details.