Part
expr[[i]] or Part[expr, i] gives the ith part of expr.
expr[[-i]] counts from the end.
expr[[i, j, ...]] or Part[expr, i, j, ...] is equivalent to expr[[i]][[j]]....
expr[[{i1, i2, ...}]] gives a list of the parts i1, i2, ... of expr.
expr[[m;;n]] gives parts m through n.
Examples
Get the second element:
{a, b, c, d}[[2]]
(* b *)Get the last element:
{a, b, c, d}[[-1]]
(* d *)Get multiple parts:
{a, b, c, d}[[{1, 3}]]
(* {a, c} *)Slice a list:
{a, b, c, d, e}[[2;;4]]
(* {b, c, d} *)Please visit the official Wolfram Language Reference for more details.